Studies of immune response by antigen loaded biodegradable polymer particles

 
Principal Investigator :  Amulya K Panda

Project Associates/Assistants
ANS Eshwari
Ruchi Chaube

Ph D Students
Yogesh K Katare
Surinder Mohan Singh
Vibhu Kanchan

Collaborators
Lalit C Garg
Pramod K Upadhyay
Ayub Quadri
Alok R Ray, IIT Delhi
SP Vyas, DHG Vishwavidyalaya, Sagar
Shantha Biotechnics Pvt Ltd, Hyderabad

V Labhateswar,
Nebraska Med Center, USA

The theme of the project is to evaluate the immunostimulatory activities associated with polymer entrapped antigens such as tetanus toxoid (TT), Hepatitis B surface antigen (HBsAg) and plasmid DNA expressing antigens for development of single shot vaccines.

The main objective is to study the immune response from biodegradable polymer particles entrapping antigens and plasmid DNA. Immune responses from polymer particles entrapping TT, HBsAg or plasmid DNA expressing HBsAg protein will be evaluated to achieve the objectives of (i) development of single shot vaccination for TT and extension of such immunization approach for Hepatitis B surface antigen (HBsAg), (ii) analysis of immune response from antigen loaded particles by employing different polymer composition, particle size and usage of various immunization protocols, evaluation of long term memory response using polymer particles base immunization, generation of cell mediated immune response using antigenentrapped polymer particles., (iii) induction of immune responses by polymer entrapped plasmid DNA expressing protein and (iv) structure function analysis of inclusion body proteins from E.coli for improved recovery of bioactive proteins.

A.    Immune response with polymer entrapped TT particles

Formulation parameters which influences the immunogenicity of polymer entrapped antigens are, size of the particles, loading and doses of antigen and mode of immunization. These parameters were extensively evaluated using polylactic acid (PLA) entrapped TT particles in single doses. It was observed that TT entrapped in PLA particles immunized with admixture of alum generates high and long lasting immune response. Nanoparticles (<1 µm size) helped in eliciting very early antibody response but the titers dropped within two months time. Very large particles (> 40 µm) do not elicit sustained antibody response. Particles in the size ranges of 4-10 µm generated long lasting immune response from single point immunization. Optimization of these above formulation parameters resulted in developing single dose of PLA entrapped tetanus toxoid formulation which elicit comparable antibody response with two doses of alum adsorbed TT.

Extensive studies were carried out to evaluate the secondary response generated from single point immunization with polymer entrapped TT. Rats immunized with polymer entrapping TT particles were boosted with 0.5 lf of saline TT after a period of nine months to evaluate the secondary responses. Secondary immune response from particles immunization having different doses, loading and size were evaluated. Among different particles formulation, the ones which gave high initial primary response gave very high secondary antibody response upon boosting with soluble antigen. Even very low amount of entrapped TT (1lf) from single point immunization gave rise to very high secondary immune response in comparison to the alum based immunization. Secondary immune response from polymer entrapped antigen was five times higher than that observed for alum adsorbed TT. Secondary antibody response generated upon soluble boosting sustained at high level for considerable period of time in comparison to alum based immunization. Antibody generated during secondary response have high affinity and were predominantly of IgG types. As observed with primary response, use of higher size particles (> 40 µm) did not elicit higher secondary response upon soluble boosting. Immunization of dummy polymer particle adsorbing equivalent dose of TT failed to elicit high antibody response indicating that entrapment of antigen inside the polymer particles is necessary for generation of high secondary response. Particles entrapping antigen inside the polymer matrix only and not in its surface elicited high secondary response upon soluble boosting. These results indicated that particles base immunization results in improved immunological memory in comparison to alum base immunization. Detail mechanism of particle uptake and immune response using polymer entrapped TT are under investigation.

B.    Development of single dose vaccine for HBsAg

Polymer particles entrapping HBsAg in were evaluated for generation of antibody response. The aim was to develop single dose HBsAg vaccine using polymer particles, which can be an alternative to the three-dose vaccination schedule. Rats were immunized with different polymer formulation and doses and antibody titers were compared with three doses of HBsAg injection on aluM. The seroprotective nature of HBsAg antibody generated from polymer particle base immunization were evaluated using AUSAB Kit (Abbot Lab, USA). Rats were immunized with lower doses of HBsAg and the antibody response were monitored for one year. It was observed that at lower doses, polymer entrapped HBsAg immunized along with alum elicited comparable HBsAg antibody titers obtained from three doses of alum adsorbed HBsAg. Immunization with very low amount of polymer entrapped HBsAg (1mg) gave rise to >500 mIU/ml of antibody titers. Secondary immune response generated from single dose polymer entrapped antigen was compared with three injection schedule of alum adsorbed HBsAg. Animals were boosted with 2 mg of soluble HBsAg after 9 months of post immunization and the antibody titers were evaluated. Very high anti-HBsAg titers were achieved within 15-20 days of post booster injection both for polymer entrapped as well alum adsorbed immunization. This indicated that single dose of polymer entrapped antigen is equally suitable to the three dose alum adsorbed HBsAg immunization for generation of high secondary immune response. Further improvement in single dose HBsAg vaccine formulation is currently under evaluation in collaboration with Shantha Biotech, Hyderabad.

C.    Immunization of plasmid DNA vaccine using polymer particles

Currently we are developing large-scale plasmid DNA preparation methods for immunization. We have been able to develop an improved process for the purification of pharmaceutical grade plasmid DNA for immunization process. From shaker flask culture, 2-3 mg of pure plasmid (encoding HBsAg gene) free from RNA and having negligible amount of endotoxin could be achieved. Pure plasmid yields are comparable to that of plasmid preparation using commercially available purification column. Different plasmids have been purified using this above procedure and their ability to transfect mammalian cells has been characterized. Currently we are optimizing process for large scale preparation of plasmid DNA for vaccination.

D.    Structure function analysis of inclusion body protein from E.coli

We are also investing the refolding of inclusion bodies protein from E.coli. Previously, we have developed a novel solubilization and refolding protocol for the high through put recovery of bioactive protein from the inclusion bodies of E.coli. To improve further the purification efficiency we are anlysing the pure, intact inclusion bodies of different protein expressed in E.coli. These inclusion bodies are being analysed in terms of size, density, charge distribution and dominant forces causing protein aggregation. It is expected that a detail analysis of the above parameters will not only help in recovering proteins from inclusion bodies but also provide information about the nature of protein aggregation. Different inclusion body solubilization process without using very high concentration of urea or guanidine hydrochloride are under progress for efficient recovery of bioactive protein from the inclusion bodies of E.coli.  

Publications

Original peer-reviewed articles

1.     Katare YK, Lalwani K, Haque IU, Ali MM and Panda AK (2003) Potentiation of immune response from polymer entrapped TT particles : towards the development of single dose vaccine. Drug Delivery 10:231-238.

2.     *Gupta V, Eshwari ANS, Panda AK and Aggarwal GP (2003) Optimization of IMAC for single step purification of recombinant ovine growth hormone from inclusion bodies of E.coli. J Chromatogr A 998:93-101 (*in press last year, since published).

3.     Chatopadhyay S, Srivastava AK, Panda AK and Bisaria VS (2004) Cytotoxicity of in vitro produced Podophylotoxin from P.hexandrum cell culture on human cancer cell line. Nat Product Res 18:51-57.

4.     Dhiman HK, Ray AK and Panda AK (2004) Characterization and evaluation of chitosan matrix for in vitro growth of MCF-7 breast cancer cell lines. Biomaterials (in press).

Reviews/Proceedings

1.     Panda AK (2003) Microbial culture and its applications. In: CBSE book on biotechnology for Class XII (Ed: Kannan K), CBSE Publication, New Delhi.

2.     *Panda AK (2003) Bioprocessing of therapeutic protein from the inclusion bodies of E.coli. Adv Biochem Eng Biotechnol 85:43-93 (*in press last year, since published).

3.     Panda AK (2004) High throughput recovery of proteins from the inclusion bodies of E.coli. In: Methods in molecular biology: Therapeutic proteins. The Humana Press Inc, USA (in press).

Patents

1.     Panda AK (2003) A process for preparation of pharmaceutical grade plasmid DNA for therapeutic application. Indian patent application # 847/DEL/2003.