Studies of immune response by antigen loaded biodegradable polymer particles


 
Principal Investigator :  Amulya K Panda

Research Associates
T Muthukumaran
S Charudarshini
S Shafiuddin
A N S Eshwari
G B Sheikh

PhD Student
Yogesh K Katare

Collaborators
Ayub Quadri
Rahul Pal
Parmod K Upadhyay
Lalit C Garg
Om Singh
Alok Roy, IIT, New Delhi
S P Vyas, DHG Vishwavidyalaya, Sagar
Shantha Biotechnics Pvt Ltd, Hyderabad

The theme of the project is to evaluate the immunostimulatory activities associated with polymer entrapped antigens such as tetanus toxoid (TT), hepatitis B surface antigen (HBsAg) and plasmid DNA expressing antigens for development of single shot vaccines.

The main objective is to study the immune response from biodegradable polymer particles entrapping antigens and plasmid DNA. To evaluate immune responses from polymer particles entrapping TT, HBsAg or plasmid DNA expressing HBsAg protein. The specific objectives of the project are (i) development of single shot vaccination for TT and extension of such immunization approach for hepatitis B surface antigen (HBsAg), (ii) analysis of immune response from antigen loaded particles by employing different strategies, and (iii) induction of immune responses by polymer entrapped plasmid DNA expressing protein.

A.    Immune response with polymer entrapped TT particles

To further improve the immune response from PLA entrapped TT particles, formulation variables were optimized. It was observed that incorporation of stabilizer and basic salt helped in better entrapment of TT in polymer particles during formulation using solvent evaporation method. With incorporation of these excipients during formulation, entrapment efficiency of TT was increased from 35% to around 75%. These particles showed improved immune response upon immunization and the in vitro release profiles of antigen correlated well with the in vivo response. Such improvement in formulation parameter while protecting the immunogenicity of the entrapped antigen were also achieved for other antigen like DT, b-hCG, HBsAg and for lysozyme.

It was also repeatedly observed that use of alum along with particles improved the antibody titers in Wistar rats. Use of alum along with antigen entrapped polymer particles not only improved the initial antibody titers very rapidly but also helped in maintaining high antibody titer throughout the post immunization period. Dose response studies with very low dose of TT in particles were carried to evaluate the immuno-stimulatory potential of particle based immunization. It was observed that at lower doses (1 lf TT), particles based immunization with alum generated almost 5 time higher antibody titers than the alum based immunization. Similar high antibody titers were also observed with different doses of TT entrapped in PLA particles. Improved anti-TT titers from particles based immunization were reproducible and similar trend in antibody response were observed for three set of animal experiments each involving 48 rats. These results showed that with proper particle formulation and immunization protocol, single dose polymer particles entrapping TT can elicit antibody response comparable to the two dose schedule of alum adsorbed TT vaccination. Such improvement in immune response with combined immunization of particles along with alum was observed for DT and HBsAg. The exact role of alum in improving the immune response from polymer particles based immunization is not known. Possibilities of different mechanism of alum on improving immune response from polymer entrapped antigen is under evaluation.

Rats immunized with polymer entrapping TT particles were boosted with 5lf of saline TT after a period of eight months to evaluate the secondary responses. It was observed that secondary immune responses generated after boosting was higher in the groups of animal immunized with particles in comparison to alum adsorbed TT group. Higher secondary response was generated from particles base immunization while boosting with 0.5 lf of soluble antigen after 8 months of primary immunization. Among different particles formulations, the ones which gave high initial primary response gave very high secondary antibody response upon boosting with soluble antigen. These results indicated that particles based immunization results in improved immunological memory in comparison to alum based immunization. The exact nature of memory is not known. Experiments involving cytokines profile of primed T cells, affinity of antibody generated after boosting are under investigation to have better understanding of the high secondary response generated from particles based immunization.

B.    Improved immune response from weak antigen using polymer particles

The immuno-stimulatory potential of polymer particles based immunization was investigated using a poor immunogen; b-hCG without conjugation to an immunogenic carrier. On immunizing rats with b-hCG with alum as adjuvant no detectable anti-hCG antibody titers were detected. Single dose immunization with PLA particles entrapping b-hCG elicited antibody response. A combination of alum and microparticles immunization resulted in high antibody titers comparable to those achieved when CFA or IFA were employed. As observed during TT particles immunization, the antibody titers from b-hCG particles gave a peak value on day 90, which was the characteristic of the polymer formulation. The anti-hCG antibody titers generated was bio neutralizing as evident from a receptor binding inhibition assay. The affinity of the antibodies towards hCG was in the range of 1010 L/M and was of the same order as antibodies generated using CFA or IFA. With a single dose immunization of particles along with alum, significant anti-hCG antibody titers were measurable for six months of post immunization. These results showed that with the judicious use of particle and adjuvant, immunogenicity of a weak immunogen could be improved. These results also suggest that for antigens where alum does not provide adjuvant effect, combination of particles with alum may be a suitable alternative for generating a high antibody response. Particles based immunization, co-encapsulating both b-HCA and TT generated better antibody response than the single antigen. This indicated that co-encapsulation of antigen and conjugate in polymer particles can be a substitute for chemical conjugation for improved immune response.

C.        Development of single dose vaccine for HBsAg

Polymer particles entrapping HBsAg were used for generation of antibody response. The aim was to develop single dose HBsAg vaccine using polymer particles, which can be an alternative to the three-dose vaccination schedule. As the HBsAg is particulate in nature, different formulation variables were optimized to check its in vitro release characteristic from polymer particles. Rats were immunized with different formulation and the antibody titers were found to be lower than that achieved with three doses of HBsAg injection on alum. The seroprotective nature of HBsAg antibody generated by polymer-based immunization were evaluated using AUSAB Kit (Abbot Lab, USA). It was observed that for more than 4 months particles based immunization resulted in >10 000 mIU/ml of HBsAg antibody titers after which it declined. Antibody titers over a period of six months were higher than the desired units required for sero-protection (10 mIU/ml). Improved formulation and dose response studies using HBsAg are currently under progress to evaluate the feasibility of single dose vaccine.

D.        Immunization of Plasmid DNA vaccine using polymer particles

Formulation and entrapment of HBsAg plasmid DNA in polymer matrix have been attempted to develop single dose DNA vaccine. Currently we are developing large-scale plasmid DNA preparation methods for immunization. Results from DNA immunization have not been reproducible and we are currently optimizing formulation parameter for improving the immune response.

Publications

Original peer-reviewed articles

1.     *Raghuvanshi RS, Om Singh and Panda AK (2001) Formulation and characterization of immunoreactive tetanus toxoid biodegradable polymer particles. Drug Delivery 8:99-106 (*in press last year, since published).

2.     Upadhyay PK, Patra AK, Mukhopadhyay R and Panda AK (2001) Real time detection and quantification of inclusion bodies expressed in E. coli by impedance measurements. Biotechnol Lett 23:839-843.

Review/Proceedings

1.     Katare YK and Panda AK (2001) Effect of alum on in vitro release profile and immunogenicity of microencapsulated tetanus toxoid. Proc Int Sym Control Rel Bioact Mater 28:1059-1060.

Patents

1.     Panda AK. A process for the formulation of single dose vaccine. Indian patent application No. 852/Del/2000 filed in Sep 2001.

2.     Panda AK, Pal R, Venkatasen N and Om Singh O. A process for improving the immunogenicity of a weak antigen. Indian patent application No. 794/Del/2001 filed in Jul 2001.